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class="ArticleMessage"><span>發(fā)布時間：2022-04-27 11:28</span><span>人氣：<i id="hits"><s id="rrzJsIdViewCount" style="display: inline;color:inherit;text-decoration:none;"><script type="text/javascript" src="/view/count.asp?t=article&id=224" async></script></s></i></span></div> <div class="ekxdb5d6rf" id="article" class="ArticleTencont"> <p> <p>一、、適用范圍</p><p>適用于汽車制造、船舶制造等運輸設(shè)備制造、家具制造、卷材制造、金屬制品、通用設(shè)備制造、專用設(shè)備制造、塑料制品、電氣機械及器材制造、計算機、通信和其他電子設(shè)備制造等行業(yè)的工業(yè)涂裝工序。</p><p>二、、主要生產(chǎn)工藝及產(chǎn)排污環(huán)節(jié)</p><p>工業(yè)涂裝行業(yè) VOCs 主要來源于 VOCs 物料（涂料、固化劑、稀釋劑、膠粘劑、清洗劑等）的儲存、輸送及使用過程，使用過程包括但不限于以下作業(yè)：</p><p>調(diào)配（混合、攪拌等）；</p><p>涂裝（噴涂、浸涂、淋涂、輥涂、刷涂、涂布等）；</p><p>粘結(jié)（涂膠、熱壓、復(fù)合、貼合等）；</p><p>干燥（烘干、風干、晾干等）；</p><p>清洗（浸洗、噴洗、淋洗、沖洗、擦洗等）。</p><p><img src="/storage/images/20220402/8c1819d69e123680cd615cfce74ff8cc.jpg"/></p><p>三、檢查要點</p><p>現(xiàn)場按照源項開展檢查，包括原輔料環(huán)節(jié)、涉VOCs 無組織排放環(huán)節(jié)、涉 VOCs 有組織排放環(huán)節(jié)和臺賬環(huán)節(jié)。</p><p>1. VOCs 含量限值及VOCs 物料判別</p><p>（1）使用的原輔材料VOCs 含量是否符合國家或地方VOCs 含量限值標準（主要通過資料檢查）</p><p>企業(yè)使用的涂料、固化劑、稀釋劑、膠粘劑、清洗劑等含 VOCs 原輔材料應(yīng)符合國家或地方VOCs 含量限值標準（國家相關(guān)標準見表 3-2）；工業(yè)涂裝企業(yè)應(yīng)使用低揮發(fā)性有機物含量的涂料。</p><p>VOCs 含量需根據(jù)國家相關(guān)標準進行測定，檢測報告應(yīng)由具有 CMA和 CNAS 資質(zhì)的第三方檢測機構(gòu)出具。如無規(guī)范的檢測報告，可通過各原輔材料包裝桶或規(guī)范的化學品安全技術(shù)說明書（MSDS）等資料上的各VOCs 物質(zhì)含量，結(jié)合原輔材料在施工（即用）狀態(tài)下的施工配比判斷，施工配比可通過查閱產(chǎn)品說明書等方式獲取。VOCs 含量也可通過現(xiàn)場采樣，經(jīng)第三方實驗室分析確定。</p><p>（2）VOCs 物料的判別（主要通過資料檢查）</p><p>根據(jù)《揮發(fā)性有機物無組織排放控制標準》（GB 37822—2019），VOCs物料為VOCs質(zhì)量占比大于等于 10% 的物料，以及有機聚合物材料。</p><p>在實際生產(chǎn)中，因不同工藝環(huán)節(jié)進出料的變化，物料VOCs 含量在不同工藝環(huán)節(jié)是不同的，需按工序逐一核實是否屬于 VOCs 物料（VOCs 質(zhì)量占比是否大于等于 10%）。</p><p>物料的VOCs 質(zhì)量占比需根據(jù)國家相關(guān)標準（見表 3-2）進行測定，檢測報告應(yīng)由具有 CMA 和 CNAS 資質(zhì)的第三方檢測機構(gòu)出具。如無規(guī)范的檢測報告，可通過各原輔材料包裝桶或規(guī)范的化學品安全技術(shù)說明書（MSDS）等資料上的各VOCs 物質(zhì)含量，結(jié)合原輔材料在施工（即用）狀態(tài)下的施工配比判斷，施工配比可通過查閱產(chǎn)品說明書等方式獲取。VOCs質(zhì)量占比也可通過現(xiàn)場采樣，經(jīng)第三方實驗室分析確定。</p><p>2. VOCs 物料的儲存與輸送</p><p>（1）VOCs 物料的儲存是否密閉（需現(xiàn)場檢查）</p><p>根據(jù)《揮發(fā)性有機物無組織排放控制標準》（GB 37822—2019），VOCs物料應(yīng)儲存于密閉的容器、包裝袋、儲罐、儲庫、料倉中。逐一檢查企業(yè)盛裝VOCs 物料（涂料、固化劑、稀釋劑、膠粘劑、清洗劑等）的容器或包裝袋在非取用狀態(tài)時是否加蓋、封口，保持密閉；盛裝過VOCs 物料的廢包裝容器是否加蓋密閉；盛裝VOCs 物料的容器或包裝袋是否存放于室內(nèi)，或存放于設(shè)置有雨棚、遮陽和防滲設(shè)施的專用場地；VOCs 物料儲庫、料倉是否為密閉空間［即利用完整的圍護結(jié)構(gòu)將VOCs 物料與周圍空間阻隔所形成的封閉區(qū)域或封閉式建筑物，除人員、車輛、設(shè)備、物料進出時，以及依法設(shè)立的排氣筒、通風口外，門窗及其他開口（孔）部位隨時保持關(guān)閉狀態(tài)］；含VOCs 廢料（渣、液）的儲存是否滿足上述要求。</p><p>（2）涉VOCs 物料轉(zhuǎn)移和輸送過程是否密閉（需現(xiàn)場檢查）</p><p>根據(jù)《揮發(fā)性有機物無組織排放控制標準》（GB 37822—2019），液態(tài)VOCs 物料應(yīng)采用密閉管道輸送，采用非管道輸送方式轉(zhuǎn)移液態(tài)VOCs 物料時，應(yīng)采用密閉容器、罐車；粉狀、粒狀VOCs 物料應(yīng)采用氣力輸送設(shè)備、管狀帶式輸送機、螺旋輸送機等密閉輸送方式，或者采用密閉的包裝袋、容器或罐車進行物料轉(zhuǎn)移。逐一檢查各VOCs 物料以及含VOCs 廢料（渣、液）的轉(zhuǎn)移和輸送是否滿足上述要求。涉 VOCs 物料密閉轉(zhuǎn)移和輸送示例見圖 3-3。</p><p>3. 涉VOCs 無組織排放</p><p>（1）各施工狀態(tài)下VOCs 質(zhì)量占比≥10% 的VOCs 物料使用過程廢氣是否收集（資料檢查和現(xiàn)場檢查相結(jié)合）</p><p>根據(jù)《揮發(fā)性有機物無組織排放控制標準》（GB 37822—2019），VOCs質(zhì)量占比≥10%含 VOCs 產(chǎn)品，其使用過程應(yīng)采用密閉設(shè)備或在密閉空間內(nèi)操作，廢氣應(yīng)排至VOCs 廢氣收集處理系統(tǒng)；無法密閉的，應(yīng)采取局部氣體收集措施，廢氣應(yīng)排至VOCs 廢氣收集處理系統(tǒng)。</p><p>逐一檢查企業(yè)施工（即用）狀態(tài)下VOCs 質(zhì)量占比≥10% 的VOCs物料（涂料、固化劑、稀釋劑、膠粘劑、清洗劑等）調(diào)配、涂裝、粘結(jié)、干燥、清洗等使用過程是否滿足上述要求。部分VOCs 物料使用過程見圖 3-4。</p><p>（2）廢氣收集設(shè)施效果是否滿足要求（需現(xiàn)場檢查）</p><p>VOCs 廢氣收集系統(tǒng)應(yīng)與生產(chǎn)工藝設(shè)備同步運行；采用外部集氣罩的，距集氣罩開口面***遠處的VOCs 無組織排放位置，控制風速不應(yīng)低于0.3 m/s；廢氣收集系統(tǒng)的輸送管道應(yīng)密閉、無破損。逐一檢查各環(huán)節(jié)VOCs 廢氣收集系統(tǒng)是否滿足上述要求。局部集氣罩控制風速的測量位置</p><p>示意見圖3-5。</p><p>（3）廢水集輸系統(tǒng)是否符合規(guī)定（資料檢查和現(xiàn)場檢查相結(jié)合）</p><p>對于工藝過程排放的含VOCs 廢水，集輸系統(tǒng)應(yīng)符合下列規(guī)定之一：①采用密閉管道輸送，接入口和排出口采取與環(huán)境空氣隔離的措施；②采用溝渠輸送，如敞開液面上方 100 mm 處 VOCs 檢測濃度≥200 μmol/mol （重點地區(qū)為 100 μmol/mol），加蓋密閉，接入口和排出口采取與環(huán)境空氣隔離的措施。檢查廢水集輸系統(tǒng)是否滿足上述要求，或可提供監(jiān)測報告等證明敞開液面上方 100 mm 處 VOCs 檢測濃度＜200 μmol/mol（重點地區(qū)為 100 μmol/mol）。</p><p>（4）廢水儲存、處理設(shè)施是否符合規(guī)定（資料檢查和現(xiàn)場檢查相結(jié)合）</p><p>含 VOCs 廢水儲存和處理設(shè)施敞開液面上方 100 mm 處 VOCs 檢測濃度≥200 μmol/mol（重點地區(qū)為 100 μmol/mol），應(yīng)符合下列規(guī)定之一：</p><p>①采用浮動頂蓋；②采用固定頂蓋，收集廢氣至 VOCs 廢氣收集處理系統(tǒng)；③其他等效措施。檢查廢水儲存和處理設(shè)施是否滿足上述要求，或可提供監(jiān)測報告等證明敞開液面上方 100 mm 處 VOCs 檢測濃度＜ 200 μmol/mol （重點地區(qū)為 100 μmol/mol）。</p><p>4. 涉 VOCs 有組織排放</p><p>VOCs 無組織廢氣收集后轉(zhuǎn)變?yōu)橛薪M織排放，執(zhí)行的排放控制要求有2 個方面：</p><p>一是排放濃度控制。VOCs 廢氣收集處理系統(tǒng)有組織排放口主要污染物排放應(yīng)符合《大氣污染物綜合排放標準》（GB 16297—1996）或相關(guān)行業(yè)排放標準、地方標準的規(guī)定。</p><p>二是處理效率要求。GB 37822—2019 規(guī)定：收集的廢氣中 NMHC 初始排放速率≥3 kg/h 時，應(yīng)配置 VOCs 處理設(shè)施，處理效率不應(yīng)低于 80%；對于重點地區(qū)，收集的廢氣中 NMHC 初始排放速率≥2 kg/h 時，應(yīng)配置VOCs 處理設(shè)施，處理效率不應(yīng)低于 80%；采用的原輔材料符合國家有關(guān)低 VOCs 含量產(chǎn)品規(guī)定的除外。</p><p><strong>四、基于以上要求，現(xiàn)場開展如下檢查：</strong></p><p>（1）排放濃度是否達標（資料檢查和現(xiàn)場檢查相結(jié)合）</p><p>根據(jù)監(jiān)測報告、在線監(jiān)測、現(xiàn)場檢測等方式，判斷對應(yīng)排氣筒的各項大氣污染物是否符合《大氣污染物綜合排放標準》（GB 16297—1996）或相關(guān)行業(yè)排放標準、地方標準的規(guī)定。GB 16297—1996 部分污染物限值見表 3-4。</p><p>檢查時還應(yīng)關(guān)注排氣筒是否有旁路稀釋排放或直接排放。</p><p>（2）是否安裝治理設(shè)施及其去除效率是否達標（資料檢查和現(xiàn)場檢查</p><p>相結(jié)合）</p><p>現(xiàn)場逐一檢查 VOCs 物料調(diào)配、涂裝、粘結(jié)、干燥、清洗等所有使用過程以及采用固定頂蓋的含 VOCs 廢水儲存和處理設(shè)施收集的廢氣是否滿足上述要求。</p><p>VOCs 治理設(shè)施的去除效率可根據(jù)監(jiān)測報告、在線監(jiān)測、現(xiàn)場檢測等方式判斷；如監(jiān)測報告未直接提供去除效率，可根據(jù)監(jiān)測報告進、出口風量和濃度進行計算。</p><p>收集的廢氣 NMHC 初始排放速率可根據(jù)監(jiān)測報告、在線監(jiān)測、現(xiàn)場檢測等方式判斷；如監(jiān)測報告未直接提供 NMHC 排放速率，可根據(jù)監(jiān)測報告風量和濃度的乘積計算。</p><p>（3）治理設(shè)施與生產(chǎn)設(shè)施是否同步運行（需現(xiàn)場檢查）</p><p>現(xiàn)場可通過“視頻監(jiān)控治理設(shè)施”“單獨安裝治理設(shè)施電表”“用能監(jiān)控治理設(shè)施”“DCS 系統(tǒng)”“在線監(jiān)測系統(tǒng)”等方式判斷治理設(shè)施的同步運行率。</p><p>（4）治理設(shè)施是否正常運行（需現(xiàn)場檢查）</p><p>現(xiàn)場檢查企業(yè)治理設(shè)施是否正常運行，相關(guān)運行參數(shù)可參照治理設(shè)施技術(shù)規(guī)范或廠家設(shè)計維護手冊，檢查要點可參考附表。</p><p>（5）治理設(shè)施是否安裝在線監(jiān)測設(shè)施并聯(lián)網(wǎng)驗收（需現(xiàn)場檢查）</p><p>納入重點排污單位名錄、排污許可證有明確要求的企業(yè)，主要排污口應(yīng)安裝在線監(jiān)測設(shè)施，并與地方生態(tài)環(huán)境主管部門聯(lián)網(wǎng)。</p><p>5. 臺賬記錄情況</p><p>（1）是否建立臺賬記錄（主要通過資料檢查）</p><p>檢查企業(yè)是否建立生產(chǎn)信息、含VOCs 原輔材料和廢氣收集處理設(shè)施三個重點環(huán)節(jié)的臺賬記錄。</p><p>（2）臺賬記錄是否規(guī)范（主要通過資料檢查）</p><p>對照表 3-5 檢查企業(yè)臺賬是否完整，內(nèi)容是否齊全，記錄是否規(guī)范。</p><p><img src="/storage/images/20220408/a0949877aa5b6fafb336658d31327272.jpg"/></p><p><img src="/storage/images/20220408/efd672f0e3e052bab8960e3965b4c65c.jpg"/></p></p> </div> <div id="ekxdb5d6rf" class="clear"></div> <div id="ekxdb5d6rf" class="reLink clearfix"> <div id="ekxdb5d6rf" class="prevLink"> <a href="/qishuifenliji/feiqichulishebei/223.html">上一篇：江蘇家具廠噴漆廢氣治理注意事項</a> </div> <div id="ekxdb5d6rf" class="nextLink"> <a href="/qishuifenliji/feiqichulishebei/225.html">下一篇：噴漆房環(huán)保處理方案</a> </div> </div> <p style="text-align: left;"> <span style="font-family: "Microsoft Yahei", PingFangSC-Regular, "Helvetica Neue", Helvetica, Arial, "Hiragino Sans GB", "Heiti SC", "WenQuanYi Micro Hei", sans-serif; color: rgb(0, 100, 0);"><span style="font-weight: bolder;">溫馨提示：</span> </span><br 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